My vote goes for Graig Faulkner. He may have the best hands of any wide receiver ever to play at Tennessee dude was money.
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Al Wilson was a 4-5 star rated safety/LB coming out of HS. He may have even been a HS AA his senior year unless I'm remembering wrong. Although he played FB and LB his sr year, the only school that recruited him as RB was Notre Dame. He didn't overachieve, everyone expected him to be awesome.
The TB on that JCM team, Wesley Barlow, was also heavily recruited. Not sure what happened to him, he may have had grade issues.
JJ McClesky, Bill Bates, Jason Julian and Craig Faulkner come to mind.
I would also through in Tim Priest. As Jon Ward says, check the stats. Tim had a knack for making interceptions. Only the Eric Berry broke some of his records.