Hard to imagine that anyone was able to do that, but crazy things do happen. The water quality is closely maintained, and the spent fuel pools are probably borated - don't know because it was out of my area of responsibility.
Other than the pool reactors at Oak Ridge, my first experience with fuel under water was at Oconee near Clemson, SC a few months after graduation from UT. Anything that breaks loose or left in the reactor coolant system is a very serious matter, so the nuclear industry developed Loose Part Monitoring Systems to detect and analyze impacts inside the reactor and steam generators. At Oconee one of the Sample Surveillance Holder Tubes had become loose and was impacting the outside of the core barrel (SSHTs hold metal samples to be removed at refueling and tested for evidence of radiation embrittlement). We were pretty certain the cause - triangulation of the impacts showed it to be non moving and we estimated the location, but we wanted a better measure of the sound propagation within the reactor. One reactor was shut down for refueling and the head removed but the fuel still in place, and they decided safe enough to quickly install a few accelerometers around the flange if we minimized the stay time while in direct line of sight with the fuel.
I got to see the nice blue glow close up and personal. We were all suited up with dosimetry and everything taped over, all tools tied off with cord. We even had the accelerometers connected to the cables before dropping them down into the pool (dry) to the top of the open reactor - the pool floor is level with the reactor flange. The dark humor was if you dropped anything in you might as well go in after it. We got the accelerometers in place and tapped the flange with an instrumented hammer (load cell to measure both the impact level and the precise time of the impact with relation to each accelerometer). I can promise that the three of us down in the pool were happy to be back out and dosimetry reading within normal limits ... and heart rate back to normal. One of those experiences you never forget.
The pool above the reactor is flooded during refueling since the fuel assemblies are pulled out of the reactor and then rotated horizontally while moved through a tunnel to the spent fuel pool. In this case the pool was dry either because refueling was not started or was complete.